Sunlight-Driven Synthesis of Triarylethylenes (TAEs) via Metal-Free Mizoroki–Heck-Type Coupling

Louis Onuigbo; Carlotta Raviola; Andrea Di Fonzo; Stefano Protti; Maurizio Fagnoni

doi:10.1002/ejoc.201800883

Sunlight-Driven Synthesis of Triarylethylenes (TAEs) via Metal-Free Mizoroki–Heck-Type Coupling

Louis Onuigbo, Carlotta Raviola, Andrea Di Fonzo, Stefano Protti, Maurizio Fagnoni

Research output: Contribution to journal › Article › peer-review

Abstract

A protocol for the preparation of substituted triarylethylenes (TAEs) was developed by using arylazo sulfones as substrates in the presence of 1,1-diarylethylenes. The process took place efficiently in the absence of any (photo)catalyst upon exposure of the reaction mixture to (simulated) sunlight.

Original language	English
Journal	European Journal of Organic Chemistry
DOIs	https://doi.org/10.1002/ejoc.201800883
Publication status	Accepted/In press - Jan 1 2018
Externally published	Yes

Keywords

Metal-free Arylation
Photochemistry
Photogenerated intermediates
Sunlight-driven processes
Triarylethylenes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry

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10.1002/ejoc.201800883

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abstract = "A protocol for the preparation of substituted triarylethylenes (TAEs) was developed by using arylazo sulfones as substrates in the presence of 1,1-diarylethylenes. The process took place efficiently in the absence of any (photo)catalyst upon exposure of the reaction mixture to (simulated) sunlight.",

keywords = "Metal-free Arylation, Photochemistry, Photogenerated intermediates, Sunlight-driven processes, Triarylethylenes",

author = "Louis Onuigbo and Carlotta Raviola and {Di Fonzo}, Andrea and Stefano Protti and Maurizio Fagnoni",

year = "2018",

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doi = "10.1002/ejoc.201800883",

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AU - Di Fonzo, Andrea

AU - Protti, Stefano

AU - Fagnoni, Maurizio

PY - 2018/1/1

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N2 - A protocol for the preparation of substituted triarylethylenes (TAEs) was developed by using arylazo sulfones as substrates in the presence of 1,1-diarylethylenes. The process took place efficiently in the absence of any (photo)catalyst upon exposure of the reaction mixture to (simulated) sunlight.

AB - A protocol for the preparation of substituted triarylethylenes (TAEs) was developed by using arylazo sulfones as substrates in the presence of 1,1-diarylethylenes. The process took place efficiently in the absence of any (photo)catalyst upon exposure of the reaction mixture to (simulated) sunlight.

KW - Metal-free Arylation

KW - Photochemistry

KW - Photogenerated intermediates

KW - Sunlight-driven processes

KW - Triarylethylenes

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Sunlight-Driven Synthesis of Triarylethylenes (TAEs) via Metal-Free Mizoroki–Heck-Type Coupling

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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