FT-IR study of anomeric pent-2-enopyranosides

P. Bruni; C. Conti; R. Galeazzi; G. Tosi

doi:10.1016/S0022-2860(00)00900-5

FT-IR study of anomeric pent-2-enopyranosides

P. Bruni, C. Conti, R. Galeazzi, G. Tosi

Istituto Nazionale di Riposo e Cura per Anziani V.E. II

Research output: Contribution to journal › Article › peer-review

Abstract

The infrared study of the solvent effect on D-glycero-pent-2-enopyranosides (α and β) that can be used as substrate precursors in the synthesis of antibiotic ristomycin components, is reported. The higher energy content in α anomers justifies differences in intra- and interbonding with respect to β anomers of the OH and the CO moieties. This behaviour is confirmed by the analysis of half band width values in different solvent mixtures. The pronounced γC(2)-H band found only in α derivatives, makes this vibrational mode of a diagnostic importance in the assignment of the configuration.

Original language	English
Pages (from-to)	271-279
Number of pages	9
Journal	Journal of Molecular Structure
Volume	565-566
DOIs	https://doi.org/10.1016/S0022-2860(00)00900-5
Publication status	Published - May 30 2001

Keywords

D-glycero-pent-2-enopyranosides
Hydrogen bonding
Infrared spectra
Molecular structure

ASJC Scopus subject areas

Structural Biology
Organic Chemistry
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics

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10.1016/S0022-2860(00)00900-5

Cite this

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title = "FT-IR study of anomeric pent-2-enopyranosides",

abstract = "The infrared study of the solvent effect on D-glycero-pent-2-enopyranosides (α and β) that can be used as substrate precursors in the synthesis of antibiotic ristomycin components, is reported. The higher energy content in α anomers justifies differences in intra- and interbonding with respect to β anomers of the OH and the CO moieties. This behaviour is confirmed by the analysis of half band width values in different solvent mixtures. The pronounced γC(2)-H band found only in α derivatives, makes this vibrational mode of a diagnostic importance in the assignment of the configuration.",

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doi = "10.1016/S0022-2860(00)00900-5",

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T1 - FT-IR study of anomeric pent-2-enopyranosides

AU - Bruni, P.

AU - Conti, C.

AU - Galeazzi, R.

AU - Tosi, G.

PY - 2001/5/30

Y1 - 2001/5/30

N2 - The infrared study of the solvent effect on D-glycero-pent-2-enopyranosides (α and β) that can be used as substrate precursors in the synthesis of antibiotic ristomycin components, is reported. The higher energy content in α anomers justifies differences in intra- and interbonding with respect to β anomers of the OH and the CO moieties. This behaviour is confirmed by the analysis of half band width values in different solvent mixtures. The pronounced γC(2)-H band found only in α derivatives, makes this vibrational mode of a diagnostic importance in the assignment of the configuration.

AB - The infrared study of the solvent effect on D-glycero-pent-2-enopyranosides (α and β) that can be used as substrate precursors in the synthesis of antibiotic ristomycin components, is reported. The higher energy content in α anomers justifies differences in intra- and interbonding with respect to β anomers of the OH and the CO moieties. This behaviour is confirmed by the analysis of half band width values in different solvent mixtures. The pronounced γC(2)-H band found only in α derivatives, makes this vibrational mode of a diagnostic importance in the assignment of the configuration.

KW - D-glycero-pent-2-enopyranosides

KW - Hydrogen bonding

KW - Infrared spectra

KW - Molecular structure

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DO - 10.1016/S0022-2860(00)00900-5

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JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

FT-IR study of anomeric pent-2-enopyranosides

Abstract

Keywords

ASJC Scopus subject areas

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